ISO 19976-2:2019 Copper, lead and zinc sulfide concentrates – Determination of cadmium一 Part 2: Acid digestion and inductively coupled plasma atomic emission spectrometric method.
This document specifies an acid digestion and inductively coupled plasma atomic emission spectrometric (ICP-AES) method for the determination of the mass fraction of cadmium in copper, lead and zinc sulfide concentrates as follows:
a) for copper sulfide concentrates, the method is applicable to the determination of mass fractions of cadmium from 0,01 % to 0,30 %;
b) for lead sulfide concentrates, the method is applicable to the determination of mass fractions of cadmium from 0,01 % to 0,30 %;
c) for zinc sulfide concentrates, the method is applicable to the determination of mass fractions of cadmium from 0,05 % to 1,00 %.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 385, Laboratory glass ware — Burettes
ISO 648, Laboratory glassware — Single-volume pipettes
ISO 1042, Labo ratory glass ware — One-mark volumetric flasks
ISO 4787, Laboratory glassware — Volumetric instruments — Met hods for testing of capacity and for use
150 8466-2, Water quality — Calibration and evaluation of analytical methods and estimation of performance characteristics — Part 2: Calibration strategy for non-linear second-order calibration functions
ISO 9599, Copper, lead, zinc and nickel sulfide concentrates — Determination of hygroscopic moisture content of the analysis sample — Gravimetric method
ISO 12743, Copper, lead, zinc and nickel concentrates — Sampling procedures for determination of metal and moisture content
ISO Guide 35, Reference materials — Guidance for characterization and assessment of homogeneity and stability
3 Terms and definitions
No terms and definitions are listed in this document.
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4 Principle
The test sample is dissolved in hydrochloric acid, nitric acid and hydrofluoric acid with a final stage perchioric acid digestion. Yttrium is added as an internal standard to solutions of dissolved samples, reference materials and calibration solutions and cadmium determined by ICP-AES.
5 Reagents
During the analysis, use only reagents of recognized analytical grade and distilled water or water of equivalent purity.ISO 19976-2 pdf download.